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The PACK tutorial demonstrates the power of the PACK plugin, using it to give a fully realised 3D-printed product a rich and interactive digital interface. Finally, the PACK development environment is a cross-platform, extensible tool for 3D-printing and visualisation of digital designs. As the PACK plugin is freely available to 3D modelers, developers and artists, they can be confident that their 3D-printing needs are met. **Disclaimer** The PACK plugin is distributed under a creative commons license (Creative Commons CC-BY-NC-SA). SUPPLEMENTARY INFORMATION {#sec1} ========================= The source code for PACK is freely available on GitHub at . We thank Josh Sleeman for his comments and suggestions on this manuscript. Supplementary Material {#sec2} ====================== Supplementary information on this article can be found online at: . [^1]: These authors contributed equally to this work. [^2]: Present address: The Medical School, University of Nottingham, City Hospital Campus, Nottingham NG7 2UH, UK. A new zirconium-based heteropolyacid incorporating P(TMS)2(OTMS)2 as a ligand. The first zirconium-based heteropolyacid, [Zr(p-TMS(2)H)(2)(2,6-C(6)H(4)Me)(2)][P(TMS)(2)(OTMS)(2)](2) (1), incorporating a bis(trimethylsilyl)amide ligand, was synthesized. [ZrCl(4)] was hydrolyzed to form the bis(trimethylsilyl)amide, followed by the condensation with the P(TMS)(2)(OTMS)(2) ligand to give the corresponding heteropolyacid. Structural characterization of 1 was performed by elemental analysis, and the molecular structure of 1 was determined by X-ray crystallography. X-ray diffraction studies reveal the distorted octahedral geometry of the heteropolyacid anion. The electrochemical behavior of 1 was investigated using cyclic voltammetry and impedance spectroscopy, and a moderate cataly




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